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Dissolved Oxygen (DO)
Oxygen is present in aquatic systems as dissolved oxygen. Oxygen is necessary to allow aquatic animals, microorganisms, and other chemical reactions to survive in the aquatic system. Oxygen is introduced into the stream system through plants (photosynthesis) and from the atmosphere. Aquatic systems with running water (such as streams and rivers) can dissolve more oxygen than aquatic systems with still water (like lakes and swamps) because the water "churns" (and has more interactions with the atmosphere). Only in deep holes or in polluted waters does dissolved oxygen levels show any significant decline.

Several complex interactions between plants, aquatic animals, and microbial organisms determine the amount of dissolved oxygen that is available in an aquatic system. DO levels also fluctuate seasonally and over a 24 hour period. The amount of DO also varies with water temperature and altitude. What does presence or absence of DO mean to an aquatic ecosystem? In general, various sources of competition for dissolved oxygen mean that some animals will not be able to survive in the aquatic system due to low dissolved oxygen.

Smith, Robert Leo. "Elements of Ecology" HarperCollins, 3rd Edition ©1992
excerpt from EPA's "Volunteer Stream Monitoring: A Methods Manual"


Temperature
Temperature is a determining factor for biological and chemical processes. As stated above, DO is one measure that fluctuates with temperature. Most aquatic organisms depend upon certain temperatures in order to sustain their life functions. Temperature also effects the process of photosynthesis and the sensitivity of certain organisms to toxic waste, parasites, and diseases.

excerpt from EPA's "Volunteer Stream Monitoring: A Methods Manual"

pH
The degree of acidity or alkalinity, or pH, of water reflects the carbon dioxide content as well as the presence of organic acids and pollution. At higher levels, water is more alkaline and at lower levels, water is more acidic. The higher the pH of stream water, the richer natural waters generally are in carbonates, bicarbonates and associated salts. Such streams support more abundant aquatic life and larger fish populations than streams with acid waters, generally low in nutrients.
Like temperature, pH levels effect both biological and chemical processes. The level of pH in an aquatic system can hinder the reproduction of certain organisms and can allow toxic substances to become more readily available for uptake by aquatic plants and animals. Over a period of time, cornerstone species in a habitat with acidic waters can disappear, causing disruptions in the food web as well the loss of other species.

Smith, Robert Leo. "Elements of Ecology" HarperCollins, 3rd Edition ©1992
excerpt from EPA's "Volunteer Stream Monitoring: A Methods Manual"

Nitrogen
Nitrogen is another essential nutrient for plant and animal development. It is necessary in the natural processes of organisms to sustain life.
However, the amount of nitrogen that is occurring in lakes, rivers and coastal waters is being aggravated through human inputs. Nitrogen and phosphorus are major ingredients in fertilizers used in farming methods, and large amounts of these chemicals are washed off farmland into streams and other tributaries through rain runoff.
Excessive amounts of nutrients such as nitrogen speed up the slow, natural nutrient enrichment process of streams and lakes, called eutrophication. Too much nitrogen in these environments can cause accelerated plant growth, algae blooms, and increase the amount of material available for decomposition (which lowers dissolved oxygen.) Often, this condition usually results in fish kills, offensive odors, unsightliness, and reduced attractiveness of the water for recreation and other public uses.

Baird, Jack V. "Nitrogen Management and Water Quality" North Carolina Cooperative Extension Service ©August 1990
excerpt from EPA's "Volunteer Stream Monitoring: A Methods Manual"

Carbon Monoxide
Carbon monoxide (CO) is a colorless, odorless and at high levels, a poisonous gas, formed when carbon in fuel is not burned completely. Less dense than air under ordinary conditions, is very slightly soluble in water and burns in air with a characteristic blue flame, producing carbon dioxide, the gas most responsible for causing the "greenhouse effect" in the Earth's atmosphere.

It is present in the exhaust of internal combustion engines (e.g., in automobiles) and is generated in coal stoves, furnaces, and gas appliances that do not get enough air (usually because of a faulty draft or for other reasons), and through natural sources such as wildfires. As a component of motor vehicle exhaust, it contributes about 60 percent of all CO emissions nationwide. In cities, as much as 95 percent of all CO emissions may come from automobile exhaust, and high concentrations of CO generally occur in areas with heavy traffic congestion. Peak CO concentrations typically occur during the colder months of the year when CO automotive emissions are greater and nighttime inversion conditions (where air pollutants are trapped near the ground beneath a layer of warm air) are more frequent.

Carbon monoxide enters the bloodstream through the lungs and reduces oxygen delivery to the body's organs and tissues. Early symptoms of carbon monoxide poisoning include drowsiness and headache, followed by unconsciousness, respiratory failure, and death. First aid for a victim of carbon monoxide poisoning requires access to fresh air; administration of artificial respiration and, if available, oxygen; and, as soon as possible, expert medical attention.

The health threat from lower levels of CO is most serious for those who suffer from cardiovascular diseases, such as angina pectoris. At much higher levels of exposure CO can be poisonous to the point where even healthy individuals may be seriously affected.

Firor, John. The Changing Atmosphere Yale University Press, © 1990. Pp. 4-5
U.S. EPA Office of Air and Radiation. 1997 National Air Quality Status and Trends
Infoplease.com Encylcopedia www.infoplease.com


Ozone
Ozone is a gas that occurs both in the Earth's upper atmosphere and at ground level. Ozone can be good or bad, depending on where it is found. "Good" ozone occurs naturally in the Earth's upper atmosphere - 10 to 30 miles above the Earth''s surface - where it shields us from harmful ultraviolet rays from the sun. "Bad" ozone occurs in the Earth's lower atmosphere, near ground level, where it is formed when pollutants emitted by cars, power plants, industrial boilers, refineries, chemical plants, and other sources react chemically in the presence of sunlight. Ozone pollution is a concern during the summer months when the weather conditions needed to form ground-level ozone - lots of sun, hot temperatures - normally occur.

Ozone, the main ingredient of smog, presents a serious air quality problem in many parts of the United States. Even at low levels, ozone can cause a number of respiratory effects such as acute respiratory problems, aggravation of existing asthma conditions, significant temporary decreases in lung capacity of 15 to over 20 percent, inflammation of lung tissue, impairment of the body's immune system defenses, making people more susceptible to respiratory illnesses, including bronchitis and pneumonia.

Several groups of people are particularly sensitive to ozone - especially when they are active outdoors - because physical activity causes people to breathe faster and more deeply. Such groups of people include active children, active adults who exercise or work vigorously outdoors and people with asthma or other respiratory illnesses.

United States Environmental Protection Agency. Office of Air & Radiation/Office of Air Quality Planning & Standards Health and Environmental Effects of Ground Level Ozone Fact Sheet

United States Environmental Protection Agency. AIRNow Homepage http://www.epa.gov/airnow/


Lead (Pb)
In the past, automotive sources were the major contributor of Pb emissions to the atmosphere. As a result of regulatory efforts to reduce the content of Pb in gasoline, the contribution from the transportation sector has declined over the past decade. Today, metals processing is the major source of Pb emissions to the atmosphere. The highest air concentrations of Pb are found in the vicinity of nonferrous and ferrous smelters, and battery manufacturers.
Exposure to Pb occurs mainly through inhalation of air and ingestion of Pb in food, water, soil, or dust. It accumulates in the blood, bones, and soft tissues. Lead can adversely affect the kidneys, liver, nervous system, and other organs. Excessive exposure to Pb may cause neurological impairments, such as seizures, mental retardation, and behavioral disorders. Even at low doses, Pb exposure is associated with damage to the nervous systems of fetuses and young children, resulting in learning deficits and lowered IQ. Recent studies also show that Pb may be a factor in high blood pressure and subsequent heart disease. Lead can also be deposited on the leaves of plants, presenting a hazard to grazing animals.

United States Environmental Protection Agency Office of Air and Radiation

Nitrogen Dioxide (NO2)
Nitrogen oxides (NOx), the term used to describe the sum of NO, NO2 and other oxides of nitrogen, play a major role in the formation of ozone. The major sources of man-made NOx emissions are high-temperature combustion processes, such as those occurring in automobiles and power plants. Home heaters and gas stoves also produce substantial amounts of NO2 in indoor settings.

Short-term exposures (e.g., less than 3 hours) to current nitrogen dioxide (NO2) concentrations may lead to changes in airway responsiveness and lung function in individuals with pre-existing respiratory illnesses and increases in respiratory illnesses in children (5-12 years old). Long-term exposures to NO2 may lead to increased susceptibility to respiratory infection and may cause alterations in the lung. Atmospheric transformation of NOx can lead to the formation of ozone and nitrogen-bearing particles (most notably in some western urban areas) which are both associated with adverse health effects.
Nitrogen oxides also contribute to the formation of acid rain. Nitrogen oxides contribute to a wide range of environmental effects, including potential changes in the composition and competition of some species of vegetation in wetland and terrestrial systems, visibility impairment, acidification of freshwater bodies, eutrophication (i.e., explosive algae growth leading to a depletion of oxygen in the water) of estuarine and coastal waters (e.g., Chesapeake Bay), and increases in levels of toxins harmful to fish and other aquatic life.

United States Environmental Protection Agency Office of Air and Radiation

Particulate Matter (PM-10)
Particulate matter (PM) is the general term used for a mixture of solid particles and liquid droplets found in the air. Some particles are large or dark enough to be seen as soot or smoke. Others are so small they can be detected only with an electron microscope. These particles, which come in a wide range of sizes ("fine" particles are less than 2.5 micrometers in diameter and coarser-size particles are larger than 2.5 micrometers), originate from many different stationary and mobile sources as well as from natural sources. Fine particles (PM-2.5) result from fuel combustion from motor vehicles, power generation, and industrial facilities, as well as from residential fireplaces and wood stoves. Coarse particles (PM-10) are generally emitted from sources, such as vehicles traveling on unpaved roads, materials handling, and crushing and grinding operations, as well as windblown dust. Some particles are emitted directly from their sources, such as smokestacks and cars. Their chemical and physical compositions vary depending on location, time of year, and weather.


Inhalable PM includes both fine and coarse particles. These particles can accumulate in the respiratory system and are associated with numerous health effects. Exposure to coarse particles is primarily associated with the aggravation of respiratory conditions, such as asthma. Fine particles are most closely associated with such health effects as increased hospital admissions and emergency room visits for heart and lung disease, increased respiratory symptoms and disease, decreased lung function, and even premature death. Sensitive groups that appear to be at greatest risk to such effects include the elderly, individuals with cardiopulmonary disease, such as asthma, and children. In addition to health problems, PM is the major cause of reduced visibility in many parts of the United States. Airborne particles also can cause damage to paints and building materials.

United States Environmental Protection Agency Office of Air and Radiation

Sulphur Dioxide (SO2)
Sulfur dioxide belongs to the family of sulfur oxide gases. These gases are formed when fuel containing sulfur (mainly, coal and oil) is burned and during metal smelting and other industrial processes. Most SO2 monitoring stations are located in urban areas. The highest monitored concentrations of SO2 are recorded in the vicinity of large industrial facilities.
High concentrations of SO2 can result in temporary breathing impairment for asthmatic children and adults who are active outdoors. Short-term exposures of asthmatic individuals to elevated SO2 levels while at moderate exertion may result in reduced lung function that may be accompanied by such symptoms as wheezing, chest tightness, or shortness of breath. Other effects that have been associated with longer-term exposures to high concentrations of SO2, in conjunction with high levels of PM, include respiratory illness, alterations in the lungs' defenses, and aggravation of existing cardiovascular disease. The subgroups of the population that may be affected under these conditions include individuals with cardiovascular disease or chronic lung disease, as well as children and the elderly.
Together, SO2 and NOx are the major precursors to acidic deposition (acid rain), which is associated with the acidification of soils, lakes, and streams, accelerated corrosion of buildings and monuments, and reduced visibility. Sulfur dioxide also is a major precursor to PM-2.5, which is a significant health concern as well as a main pollutant that impairs visibility.

United States Environmental Protection Agency Office of Air and Radiation


TSP (Total Suspended Particulates)
TSP is a measure of the particulate content of ambient air. Air monitoring networks were changed in 1987 to measure PM-10 (replacing the earlier TSP monitors). The new standard focuses on smaller particles that are likely responsible for adverse health effects because of their ability to reach the lower regions of the respiratory tract.

United States Environmental Protection Agency Office of Air and Radiation

Toxics Release Inventory (TRI)
Following a fatal chemical-release accident in Bhopal, India, the Emergency Planning and Right-to-Know Act (EPCRA) provisions were enacted to promote, among other things, providing the public with information to provide the public with information on release of toxic chemicals in their communities. This established the Toxics Release Inventory (TRI) Program, a publicly available national database that identifies facilities, chemicals manufactured and used at the identified facility, and the annual amounts of these chemicals released (in routine operations as well as accidents and other one-time events.)
The TRI contains information on specific toxic chemical releases and other waste management activities from the manufacturing sector of the U.S. economy and, since 1994, federal facilities. Each year, facilities that meet certain thresholds must report their releases and other waste management activities for listed toxic chemicals to EPA and to the state or tribal entity where the facility is located. Beginning in 1991, covered facilities were required to report quantities of TRI chemicals recycled, combusted for energy recovery, and treated on- and -offsite.

excerpt from "1987-1996 Toxic Release Inventory User Manual" U.S. Environmental Protection Agency, © July 1999

Wetlands
Wetlands are defined as "Those areas that are inundated or saturated by surface or ground water at a frequency and duration sufficient to support, and that under normal circumstances do support, a prevalence of vegetation typically adapted for life in saturated soil conditions. Wetlands generally include swamps, marshes, bogs, and similar areas.." It is divided into estuarine and freshwater systems, which may be further subdivided by soil type and plant life into bogs, swamps, and marshes. Because wetlands have poor drainage, the area is characterized by sluggish or standing water that can create an open-water habitat for wildlife. Highly productive and complex ecosystems, wetlands help to regulate the water cycle, filter the water supply, and prevent soil erosion. More significantly, however, wetlands serve as spawning and feeding grounds for nearly one third of the endangered animal and plant species in the United States, and their ecological value in most other countries is comparable.

The VEQI used wetland loss as a measure of ecosystem-level change. Wetland loss has been included in several indexed measures of environmental quality. Wetlands act as buffers from and filters of pollution. Wetlands also reduce flooding, contribute to the groundwater supply recharge and provide excellent habitat for fish, shellfish, birds and insects.

Virginia has about 1 million acres of wetlands; one-quarter are tidal and three-quarters are non-tidal. Forested wetlands (swamps) are the most common wetlands in the State. Both shores of the Chesapeake Bay have extensive estuarine wetlands. Conversion to non-wetland uses (agricultural, urban, industrial, and recreational), channelization and ditching, and other causes have resulted in the loss of about 42 percent of Virginia's wetlands since the 1780's. Other estimates gauge current wetland acreage as 50% of 1780s holdings.

Many wetlands were destroyed by urban growth and farming before their value was recognized. More than half of U.S. wetlands in the lower 48 states have been lost since colonial times. Federal wetlands policy today is based on the wetlands provisions (1987) of the Clean Water Act. The working concept is that of ""no net loss,"" a concept that has been interpreted in various ways by each federal administration.

http://www.epa.gov/owow/wetlands/facts/fact11.html

Infoplease.com Encylcopedia www.infoplease.com
Firor, John. The Changing Atmosphere Yale University Press, © 1990. Pp. 4-5



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